Our popular blog 5 Steps to Start Silver Soldering covers soldering with a brief explanation of pickling metal. This time around, we’re expanding on the pickling process. Pickling is simply dissolving firescale from the top layer of your piece after it has been heated. It’s called pickling because jewelers used to remove firescale with a solution of alum, which is the same compound used to make pickles.
Firescale occurs to some degree every time your piece is heated, whether it is made of silver, brass or copper. Heating metal causes copper oxides to rise and mix with the air to create a purple, gray or blue color on the surface of the metal.
Sterling silver tends to get a lot of firescale on it and here’s why: Metalsmiths heat pieces several times during the jewelry making process. When metal becomes work-hardened, we anneal it. When we solder joints together, we torch it. Just using a Flex Shaft or a bench polisher heats it up, too, so we are constantly bringing the copper oxides to the surface where it tries to balance itself with the silver already present. We can remove this firescale with a nice, warm bath of jeweler’s pickling solution.
The pickling process and what you’ll need:
Safety gear: Wear an apron to protect your clothes and safety glasses to protect your eyes. If you have long hair, make sure you tie it back. Work in a well-ventilated area and be prepared to follow any other precautions listed on the package.
Pickle pot: Pickle works best at a warm temperature, so use a small crock pot that will warm up the solution without boiling it. Please note that this crock pot is now a permanent part of your jewelry studio. It is no longer safe to use for food preparation of any kind!
Pickle solution: We use Sparex #2 in our studio, which is a sodium bisulfate acid. Follow the manufacturer’s instructions on the package to mix the dry compound into water. We also offer Citric Acid Pickle. It may take more material to make a strong solution and will take longer to remove firescale, but it will not harm your clothes, bench surfaces and flooring like other acids will.
Quench bowl: Use a bowl of water to remove acid from your piece after the pickling process.
Copper tongs: Sparex pickle reacts to steel tweezers/tongs causing it to plate copper onto your metal. So, only add/remove your pieces with copper tongs (although I’ve heard plastic and wood work too). If steel gets into your solution, most people recommend making a new batch of Sparex pickle. Citric acid pickle is safe to use with steel.
Steps in the pickling process:
- Prep your work area. Turn on fans and get your safety gear ready.
- Mix your pickle solution by following the manufacturer’s instructions on the package.
- Turn your crock pot to the low setting. The solution should be warm but not boiling.
- Solder your piece.
- Allow the soldered piece to naturally cool for a few minutes in a pumice cup or on any heat resistant surface. Note: You don’t want to quench it or pickle it too soon because they both cause too much steam that can remove delicate parts on your piece, plus, they can cause the metal to become stressed too quickly. It’s better to allow natural cooling before pickling.
- Pick up the metal with copper tongs and carefully drop it into the pickle solution.
- Check on it every couple of minutes until the firescale is removed.
- Use only your copper tongs to pull it from the pickle pot and rinse it in the water. Don’t be surprised if the piece is white when removed. The pickle causes the top layer of copper to be removed from the piece, so what is left is pure silver on the top layer causing the white appearance as you pull it from the pickle pot.
- Now, you’re ready to polish and finish your piece!
Disposing of your pickle solution and what you’ll need:
Small strainer: to remove any solid metal pieces from your solution.
Baking soda: Both types of jeweler’s pickle will last for weeks or months before you need to change it. If you’re using Sparex, you’ll need to neutralize it with baking soda before disposal. To neutralize it, add heaping tablespoons of baking soda to your crock pot until the solution no longer reacts by bubbling up. Citric acid pickle doesn’t need to be neutralized.
Steps for proper disposal:
- Pour down the drain.
or dilute and pour into your garden, especially on acid loving plants like roses!
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